You might find it helpful first to read
Casting in Fog on Just One Week, which clarifies all the terminology.
The set up of floating line, polyleader and mono tippet is commonly used. Indeed, I've caught 80+% of my salmon using that approach. There are a couple of things to bear in mind with polyleaders. First, their sink rate is measured in static water, so they don't sink as fast or as far in moving water, which generates hydrodynamic lift. In essence, you won't get very deep with a polyleader: for example, with a 10' brown fast sink polyleader in medium paced water and a conventional double fly, it's likely you will be fishing at a depth of around a foot at the mid-point of the swing. Second, longer sinks further than shorter. For example, a 5' green slow sink polyleader will only take your double fly 5-6" below the surface, which is no more than you will achieve with a 12' fluorocarbon tippet. Third, most salmon rivers are generally quite shallow (apart from specific deep pools); we tend to overestimate the depth in front of us; a taking salmon will come up 5-6' to your fly; and you need to present your fly above the fish for reasons of detectability and visibility.
The main reasons for using a polyleader are to get your fly down through the surface turbulence to achieve a smooth presentation; and to ease the casting turnover of larger and heavier flies. They're not the answer on those rarer occasions when you need to get deep.
Going seriously deep is the domain of sinking lines. Sinking tips on a floating line are a compromise, but while useful, easy and flexible, they don't get you down very far. You need to go heavy in deep water; in cold water in spring when salmon tend to lie near the bottom; or to counteract the effects of very fast flows. But unless you're fishing big rivers like the Tweed, Tay and Spey in early spring, or in Norway where the pace of the water is unlike anything you encounter in UK, you are unlikely to need a sinking line very often and you may not need to make the investment.